I just did that the other day but I do not remember the exact name of the folder. It was something like 'My Documents'. Simply copy and paste the PDF there and you will see it on your library.
Just do not expect the PDFs to look all that great. The Nook cannot format PDFs properly on the screen thanks to a poor Adobe implementation for such readers. Hopefully a much improved Acrobat Reader will be delivered in a future firmware.
CR
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